Day one, minute one. The easiest first chord, the right way to hold it, and a song you can play with just this one.
Em uses only 2 fingers and all 6 strings. It sounds full, forgiving, and appears in thousands of songs.
Strum slowly. Every string should ring clearly. If one sounds muted, check that your finger is curved and pressing just behind the fret bar, not on top.
"Sunshine of Your Love" intro riff, "Horse With No Name" verse (A then Em alternating — but Em alone works as a drone). Even strumming Em in a steady rhythm over a metronome for 5 minutes trains your hand better than bouncing between 3 chords badly.
D, then G, then C. Once you have Em–D–G–C, you can play hundreds of pop songs.
Normal for the first 2 weeks. Play 10 minutes, rest, come back. Calluses form in about 10 days of daily practice.